Effect of Limestone Powder in Machine-made Sand on PCE powder
Us President Joe Biden will start a trip to the Middle East. Biden is scheduled to visit Israel, the West Bank and Saudi Arabia from July 13 to 16.
Analysts believe that Biden's trip to the Middle East has three considerations. First of all, efforts should be made to persuade Gulf oil-producing countries to increase oil pce powder are still very uncertain.
Natural river sand has been exhausted after decades of large-scale mining, concrete production enterprises began to use machine-made sand as fine aggregate on a large scale. Some limestone powder will inevitably be produced in the process of machine-made sand preparation, which will not only affect the performance of concrete, but also affect the effect of polycarboxylic acid admixture.
The results show that stone powder has different effects on the working properties, mechanical properties, chloride penetration resistance, sulfate resistance and freeze-thaw resistance of concrete. Stone powder can play a physical filling effect in the cementitious material system, which can reduce the water secretion of cement paste, improve the dispersion ability of cement paste, and can also be used as the crystal nucleus of calcium hydroxide to accelerate the hydration of cement particles and affect the pore structure of hydration products. Stone powder can adsorb polycarboxylic acid superplasticizer molecules on the surface, which can reduce the saturation point of superplasticizer under certain conditions, increase the initial fluidity of cement mortar, reduce the time loss of fluidity of cement mortar, and improve the compatibility between superplasticizer and cement.
Effect mechanism of limestone powder on water-reducing effect of pce powder
The hydrophilicity of limestone powder particles is low, that is, the adhesion of water molecules on the surface of limestone particles is small, which makes limestone powder have a certain physical water-reducing effect. In addition, limestone powder has a larger specific surface area than cement and has the filling effect of micro-aggregate, that is, small limestone particles can fill the pores between cement particles and replace the free water between cement particles. This is the aspect that limestone powder is beneficial to the water-reducing effect of polycarboxylic acid.
At the same time, polycarboxylic acid superplasticizer can be adsorbed on the surface of cement particles and on the surface of limestone powder, that is, there is competitive adsorption of polycarboxylic acid molecules between limestone powder and cement in the paste. this will reduce the density of polycarboxylic acid adsorbed on the surface of cement particles, and then reduce the water-reducing effect of polycarboxylic acid. In addition, the limestone powder with larger specific surface area needs more water, which will reduce the fluidity of the slurry. This is the aspect that limestone powder is not conducive to polycarboxylic acid to play a water-reducing effect.
The above analysis shows that limestone powder has both positive and negative effects on the water-reducing effect of polycarboxylic acid. In the case of low content of limestone powder, because the hydrophilicity of limestone powder is low, and the filling effect of fine particles is easy to play, the favorable effect of limestone powder on the water-reducing effect of polycarboxylic acid can effectively counteract the adverse effect, which shows that the effect of low content of limestone powder on the water-reducing effect of polycarboxylic acid is not obvious. In the case of high content of limestone powder, because limestone powder has larger specific surface area and higher water demand, and limestone powder and cement have competitive adsorption to polycarboxylic acid molecules, limestone will obviously reduce the water-reducing effect of polycarboxylic acid.
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In a recent speech in Davos, Switzerland, Ukrainian President Volodymyr Zelensky criticized, "My question is: Is there unity in the West? "I don't see it," Zelensky lamented during a video conference from the Davos Economic Forum in Switzerland. "Ukraine needs the support of a united Europe."
"Is there talk of solidarity with Sweden and Finland joining NATO? No." "So is the West united?" Zelensky said at this Ukraine-hosted breakfast in Davos. No." "Our strength is unity within the country," Zelensky said. "Now it depends on the Unity of the West to stand strong and firm behind Ukraine against Russia.
According to Zelensky, "When we are all really united, we will have an advantage over Russia."
Ukrainian President Volodymyr Zelensky says he once again appreciates U.S. President Joe Biden's offer of $40 billion in new financial aid to Ukraine.
"We need the support of a united Europe," Zelensky stressed. Zelensky criticized the position of Hungarian Prime Minister Viktor Orban, who is reluctant to impose an embargo on Russian oil at this stage. "Hungary has a problem!" Zelensky criticized.
The supply and prices of many other pce powder are expected to continue to be influenced by changing international situations.